The Community of Champions currently focuses on Sub-Saharan Africa. However, guest speakers, observers and stakeholders from other regions may be invited to participate in relevant activities.

Membership in the Community is by invitation/nomination by the partners of the Community. Nominated government officials usually play a direct role in the realisation of the regional and national energy access targets, with interest and/or commitment to off-grid solar electrification in their respective countries. Nominated government officials are usually from ministries responsible for energy, rural electrification authorities and other government agencies, including bureaus of standards, ministries responsible for finance or rural development.